Group 4 metallocene catalysed full dehydrogenation of hydrazine borane.

نویسندگان

  • Johannes Thomas
  • Marcus Klahn
  • Anke Spannenberg
  • Torsten Beweries
چکیده

A study of the full dehydrogenation of hydrazine borane (H2N-NH2·BH3) to give H2 and N2 as gaseous products catalysed by a variety of group 4 metallocene alkyne complexes of the type CpM(L)(η(2)-Me3SiC2SiMe3) (Cp' = substituted or unsubstituted η(5)-cyclopentadienyl; M = Ti, no L; M = Zr, L = pyridine) and group 4 metallocene hydrides is presented. Volumetric data show that the amount of hydrogen released is strongly dependent on both, the metal and the cyclopentadienyl ligand.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 41  شماره 

صفحات  -

تاریخ انتشار 2013